CURRICULUM VITAE
SURNAME: Miranda
FIRST NAME: Miguel A.
NATIONALITY: Spanish
DATE OF BIRTH: April
17, 1952
PLACE OF BIRTH: Albacete, Spain
FAMILY STATUS:
Married, two children
ACADEMIC
DEGREES:
M. Sc., Universidad de Valencia, 1974, Ph.
D., Universidad Autónoma de Madrid, 1978
PRESENT POSITION:
Professor of
Chemistry, Universidad Politécnica de Valencia, Spain
EMPLOYMENT RECORD:
Nov 74 - Jun 78, research associate
(PFPI fellowship), Institute of Organic Chemistry, CSIC, Madrid (R. Martínez-Utrilla)
Sept 78 - Aug 79, post-doc (DAAD
fellowship), Institute
of Organic Chemistry,
Universität des Saarlandes, Saarbrücken (H. Dürr)
Oct 79 - Dec 84, assistant
professor, Department of Organic Chemistry (Faculty of Pharmacy), Universidad
de Valencia
Jan 85 - Dec 89, associate
professor, Department of Organic
Chemistry (Faculty of Pharmacy), Universidad de Valencia
Sept 86 - Aug 87, invited professor
(A. v. Humboldt fellowship), Institute
of Organic Chemistry,
Universität Würzburg (W. Adam)
Jan 90 - - full professor, Department of
Chemistry/Institute of Chemical Technology UPV-CSIC, Universidad
Politécnica de Valencia
RESEARCH INTERESTS:
1) Photochemistry of organic compounds, with special emphasis on
chiral recognition in the excited states, photoinduced electron transfer,
photochemistry of bichromophoric compounds, photoreactivity in confined spaces
(e.g. zeolites) and synthetic applications and 2) Photobiology, with special emphasis on photoinduced damage to
biomolecules (lipids, proteins, nucleic acids) and the molecular bases of
photosensitization by drugs (phototoxicity, photoallergy).
PROFESSIONAL
SOCIETIES:
Real
Sociedad Española de Química
European Photochemical Association
American Society for Photobiology
European Society for Photobiology
Sociedad
Argentina de Investigación en Química Orgánica (Honorary
Member)
Grupo Español de
Fotobiología
DISTINGUISHED POSITIONS
Associate Editor of Photochemistry and Photobiology, the
official organ of the American Society for Photobiology, 1997-2002.
President of the Grupo
Especializado de Fotoquímica (Real Sociedad Española de
Química), 1995-1999.
Secretary of the European Society for Photobiology, 1997-2001.
Chairman, XX IUPAC
Symposium on Photochemistry, 2004.
ACTIVITIES AS EVALUATOR/REFEREE:
Reviewer for the Journal of the
American Chemical Society, Angewandte Chemie (International Edition in
English), Journal of Organic Chemistry, Chemistry- A European Journal, Journal
of Physical Chemistry, ChemPhysChem, European Journal of Organic Chemistry,
Bioorganic and Medicinal Chemistry Letters, Helvetica Chimica Acta, Pure and
Applied Chemistry, Journal of Physical Organic Chemistry, Liebigs Annalen der
Chemie, Recueil des Travaux Chimiques des Pays Bas, Photochemical and
Photobiological Sciences, Journal of Chromatography A, Photochemistry and
Photobiology, Journal of Photochemistry and Photobiology, A: Chemistry, Journal
of Photochemistry and Photobiology, B: Biology, Applied Catalysis B:
Environmental, Journal of Medicinal Chemistry, Anales de Química
International Edition, European Journal of Medicinal Chemistry, Journal of Pharmaceutical Sciences, Biochemical
Pharmacology, European Journal of Pharmaceutical Sciences, Toxicology in vitro,
Food and Chemical Toxicology, Cell Biology and Toxicology, Chemosphere, etc.
Evaluator of research proposals for
the Agencia Nacional de Evaluación y Prospectiva (the Spanish National
Agency for the evaluation of scientific proposals), the Italian Ministry for
University, Research and Technology (MURST), the Agencia Nacional de
Promoción Científica y Tecnológica Argentina, the National
Research Council of Canada, etc.
ORGANIZATION OF SCIENTIFIC MEETINGS
Member of the
Scientific Committee and Symposium Chairman. XXVI Reunión Bienal
de la Real Sociedad
Española de Química. Cádiz (Spain),
September 1997.
Member of the Scientific Committee
of the 2nd Euro-Mediterranean Conference on Applications of Photobiology and Laser Technologies
in Medicine and Environment. Cairo (Egypt),
February 1998.
Member of the
Local Organizing Committee and Session Chairman. XVII
IUPAC Symposium on Photochemistry. Sitges (Barcelona, Spain),
July 1999.
Chairman of the IV Congreso
de Fotoquímica, organized by the Grupo Especializado de
Fotoquímica of the Real Sociedad Española de Química.
Gandía (Valencia), March 1999.
Member of the Organizing and the Scientific Committees.
Symposium Chairman. 8th
Congress of the European Society for Photobiology. Granada
(Spain),
September 1999.
Co-Chairman, 17th International
Conference on Radical Ions . Peñíscola (Spain), June
2000.
Member of the
Local Organizing Committee of INVITOX 2000. Pueblo Acantilado, Spain, October 2000.
Member of the International Scientific Committee, XIX IUPAC Symposium on
Photochemistry, Budapest (Hungary), July
2002.
Chairman, XX IUPAC
Symposium on Photochemistry. Granada (Spain), July
2004.
LANGUAGES:
Spanish, English,
German and French
LIST OF SCIENTIFIC PUBLICATIONS:
1. R.
Martínez-Utrilla, M. A. Miranda "Indirect hydroquinone
succinoylation via a photo-Fries rearrangement. Application
to the synthesis of enol lactones", Tetrahedron
Lett. 2281 (1980).
2. H. García, R. Martínez-Utrilla, M. A. Miranda "The
photochemistry of a-acetoxystyrene", Tetrahedron
Lett. 3925 (1980).
3. R. Martínez-Utrilla, M. A. Miranda "Photochemistry of
5-aryl-2(3H)-furanones", Tetrahedron
37, 2111 (1981).
4. H. García, R. Martínez-Utrilla, M. A. Miranda
"Photocyclization of enol acetates of o-acetoxyacetophenones to
chromones", Tetrahedron Lett. 1749 (1981).
5. M. A. Miranda, A. Solano, R. Martínez-Utrilla
"Fotoquímica de 6-aril-3,4-dihidropiran-2-onas", An. Quim. 78C,
132 (1982).
6. M. R. Díaz-Mondéjar, M. A. Miranda
"2´-Acetoxy-2-hydroxy-5-methoxybenzophenone. Photochemical synthesis, transacylation and
cyclization to 2-methoxyxanthone", Tetrahedron
38, 1523 (1982).
7. J. Primo, R. Tormos, M. A. Miranda "A new synthesis of
4-chromanones", Heterocycles 19, 1819 (1982).
8. H. García, R. Martínez-Utrilla, M. A. Miranda, M. F.
Roquet-Jalmar "Intra- and intermolecular photoreactions of o-benzoyloxyacetophenone
derivatives", J. Chem. Research (S) 350 (1982).
9. H. García, R. Martínez-Utrilla, M. A. Miranda, M. F.
Roquet-Jalmar "Influence of enol acetylation on the photo-Fries
rearrangement of an o-acylaryl benzoate", Liebigs Ann. Chem. 2238 (1982).
10. A. Corma, M. A. Miranda, J. Pérez-Pariente "Influence of
metal dispersion on the decay of a Pt/NaY zeolite catalyst during
dehydrogenation of methylcyclohexane", React.
Kin. Catal. Lett. 23, 153 (1983).
11. M. R. Díaz-Mondéjar, M. A. Miranda "Photolysis of
2-aryloxy- or 2-arylthio-1,3-benzodioxan-4-ones",
Heterocycles 22, 1125 (1984).
12.
A.
Corma, H. García, M. A. Miranda "Influence of carbenium ion
stabilization on the acid-catalyzed hydrolysis of a-acetoxystyrenes", J. Molec. Catal. 31, 161 (1985).
13. H. García, R. Martínez-Utrilla, M. A. Miranda
"Photolysis of enol acetates and a-bromo derivatives of
o-acyloxyacetophenones", Liebigs
Ann. Chem. 589 (1985).
14. H. García, S. Iborra, M. A. Miranda, J. Primo
"Application of the photo-Fries rearrangement of aryl dihydrocinnamates to
the synthesis of flavonoids", Heterocycles
23, 1983 (1985).
15. J. Bosch, M. Amat, E. Sanfeliu, M.
A. Miranda "Studies on the synthesis of pentacyclic Strychnos indole
alkaloids. Photocyclization of N-chloroacetil-1,2,3,4,5,6-hexahydro-1,5-methanoazocino[4,3-b]indole
derivatives", Tetrahedron 41, 2557 (1985).
16. H. García,
R. Martínez-Utrilla, M. A. Miranda "Cyclic acetals as carbonyl
blocking groups in the photo-Fries rearrangement of acyl substituted aryl
esters", Tetrahedron 41, 3131 (1985).
17. H. García,
J. Primo, M. A. Miranda "The photo-Fries rearrangement in the presence of
potassium carbonate: a convenient synthesis of o-hydroxyacetophenones", Synthesis 901 (1985).
18. H. García,
M. A. Miranda, J. Primo "The photo-Fries rearrangement of
acetoxyacetophenones using cyclic acetals as carbonyl blocking groups, in the
presence of potassium carbonate. An improved procedure for the synthesis of
diacylphenols", J. Chem. Research (S) 100 (1986)
19. P. Camps, R.
Lozano, M. A. Miranda "Photolysis of cis-bicyclo[3.3.0]octane-3,7-diones",
J. Chem. Research (S) 250 (1986).
20. C. Belled, M. R. Díaz-Mondéjar, M. A. Miranda, A. Corma
"Silica gel catalyzed transacylation of 2,2´-disubstituted
benzophenones", J. Molec. Catal. 35, 191 (1986).
21. M. Alvaro, H. García, M. A. Miranda, J. Primo "Neighbouring
group participation in the photolysis of aryl esters of unsaturated 1,4-dicarboxylic acids", Recl. Trav.
Chim. Pays Bas 105,
233 (1986).
22. P. Camps, M. A.
Lluch, M. J. Climent, M. A. Miranda "Unexpected formation of
chroman-4-ones during the synthesis of 4-hydroxymethyl-2H-chromenes from
4-arylbut-2-yn-1-ols", Tetrahedron
Lett. 2041 (1986).
23. H. García, S. Iborra, M. A. Miranda, J. Primo
"Photolysis of cyclic acetals of aryl benzoylacetates as the key step in a
new synthesis of flavones", Heterocycles
24, 2511 (1986).
24. H. García,
S. Iborra, J. Primo, M. A. Miranda "6-Endo-dig versus 5-exo-dig ring
closure in o-hydroxyaryl phenylethynyl ketones. A new
approach to the synthesis of flavones and aurones", J. Org. Chem. 51, 4432
(1986).
25.
M.
Alvaro, H. García, S. Iborra, M. A.
Miranda, J. Primo "New photochemical approaches to the synthesis of
chromones" Tetrahedron 43, 143 (1987).
26. J. V. Castell, M.
J. Gómez-L., M. A. Miranda, I. M. Morera "Toxic effects of the
photoproducts of Chlorpromazine on cultured hepatocytes", Hepatology 7, 349 (1987).
27. M. J. Climent, H. García, M. A. Miranda, J. Primo "Novel
photoreactions of chromene derivatives. The photolysis of
4-acetoxy-2H-chromene", Tetrahedron 43, 999 (1987).
28.
A. M.
Amat, G. Asensio, M. J. Castelló, M. A. Miranda, A. Simón-Fuentes
"Modified photobehaviour of carboxylic acid derivatives upon
protonation", Tetrahedron 43, 905 (1987).
29. J. V. Castell, M.
J. Gómez-L., V. Mirabet, M. A. Miranda, I. M. Morera "Photolytic
degradation of Benorylate. Effects of the photoproducts on
cultured hepatocytes", J. Pharm.
Sci. 76, 374 (1987).
30. M. A. Miranda, J. Primo, R. Tormos "Influence of the stereochemistry
on the rate of cyclization of cis- and trans-o-hydroxyaryl alkenyl ketones. Mechanistic implications", Tetrahedron
43, 2323 (1987).
31. P. Camps, C.
Iglesias, R. Lozano, M. A. Miranda, M. J. Rodríguez "A new
synthetic entry into the tricyclo[3.3.0.03,7]octane
skeleton", Tetrahedron Lett. 1831 (1987).
32. W. Adam, A.
Casado, M. A. Miranda "Cerium(IV)-catalyzed
single electron transfer (SET) on acenaphthene and
1,4-dihydro[1,8-d,e]diazepine: chemical evidence for distinct radical
cations", Angew. Chem.,
Int. ed. Engl. 26, 797 (1987).
33. M. Alvaro, V. Baldoví, H. García, M. A.
Miranda, J. Primo "A novel photochemical 1,4-acyl migration in enol
esters. The photolysis of enol
acetates of 3-phenylpropiophenones", Tetrahedron
Lett. 3613 (1987).
34. A. M. Amat, G. Asensio, M. J. Castelló, M. A.
Miranda, A. Simón-Fuentes "C4H7O2+ ions. Thermochemistry in sulfuric acid solution and CIMS relationships", J. Org. Chem. 52, 4790 (1987).
35. J. V. Castell, M.
J. Gómez-L., M. A. Miranda, I. M. Morera "Photolytic degradation of
Ibuprofen. Toxicity of the isolated photoproducts on
fibroblasts and erythrocytes", Photochem. Photobiol. 46, 991 (1987).
36. W. Adam, M. A.
Miranda "Thermal and photochemical reactions of bicyclic azoalkanes in
concentrated sulfuric acid", J. Org.
Chem. 52, 5498 (1987).
37. W. Adam, S.
Grabowski, M. A. Miranda, M. Rübenacker "Generation of the 1,4-diphenylcyclohexane-1,4-diyl radical cation by
cerium(IV)-catalyzed denitrogenation of the azoalkane
1,4-diphenyl-2,3-diazabicyclo[2.2.2]oct-2-ene and its reluctance to undergo
Cope rearrangement", J. Chem. Soc.,
Chem. Commun. 142 (1988).
38. M. A. Miranda, J. Primo, R. Tormos "Studies on the synthesis of
precocenes. The photo-Fries rearrangement of esters of a,b-unsaturated
carboxylic acids and m-oxygenated phenols", Heterocycles 27, 673
(1988).
39. P. Camps, C.
Iglesias, M. J. Rodríguez, M. D. Grancha, M. E. Gregori, R. Lozano, M.
A. Miranda, M. Figueredo, A. Linares " A short synthesis of dimethyl
tricyclo[3.3.0.03,7]octane-1,5-dicarboxylate", Chem. Ber. 121,
647 (1988).
40. A. Amat, G. Asensio, M. A. Miranda, M. J. Sabater, A.
Simón-Fuentes "Thermolysis of unsaturated dicarboxylic acids in
sulfuric acid and oleum. A comparison with the CIMS
fragmentation patterns", J. Org.
Chem. 53, 5480 (1988).
41. M. J. Climent, H. García, S. Iborra,
M. A. Miranda, J. Primo "Photosensitized dehydrogenation of flavanones to
flavones using 2,4,6-triphenylpyrylium
tetrafluoroborate (TPT)", Heterocycles
29, 115 (1989).
42. H. García,
S. Iborra, M. A. Miranda, J. Primo "Intermolecular reactions of radical
cations in the gas phase. Mass spectral evidence for an
ion-molecule process leading to the dimerization of aurones", Org. Mass Spectrom. 24, 115 (1989).
43. C. Belled, M. A. Miranda, A. Simón-Fuentes
"Fototransposición de Fries de derivados de tiosalicilato de
fenilo. Una nueva aproximación a la síntesis de
tioxantonas", An. Quím. 85 C, 39 (1989).
44.
L.
Fillol, R. Martínez-Utrilla, M. A. Miranda, I. M. Morera
"Photochemistry of 5-(2-acetoxyaryl)-2(3H)-furanones. 2. Isolation of chromone-3-acetic acids and their
photodecarboxylation to 3-methylchromones", Heterocycles 29, 511
(1989).
45. M. A. Miranda, J. Primo, R. Tormos "Photochemistry of
7-acetoxybenzopyran derivatives. Synthesis of
Eupatoriochromene and Encecalin", Tetrahedron
45, 7593 (1989).
46. H. García,
S. Iborra, M. A. Miranda, J. Primo "2,4,6-Triphenylpyrylium
tetrafluoroborate sensitized photolysis as a novel method for the hydrolytic
cleavage of acetals and thioacetals", New
J. Chem. 13, 805 (1989).
47. L. Fillol, R. Martínez-Utrilla, M. A. Miranda, I. M. Morera
"Photochemical versus aluminum chloride-catalyzed Fries rearrangement of
aryl hydrogen succinates. Synthesis of 2(3H)-furanones",
Monatsh. Chem. 120, 863 (1989).
48.
M. V.
Baldoví, H. García, M. A. Miranda, J. Primo "Electron
transfer photofragmentations of 3-phenylpropiophenones", Monatsh. Chem. 121, 371
(1990).
49. C. Belled, M. A. Miranda, A. Simón-Fuentes
"Fototransposición de Fries de esteres fenólicos de los
ácidos antranílico y N-acetilantranílico. Aplicaciones a
la síntesis de heterociclos", An.
Quím. 86 C, 431
(1990).
50. G. Serrano, J. Bonillo, A. Aliaga, J. Cuadra, C.
Pujol, P. Cervera, M. A. Miranda "Piroxicam-induced photosensitivity and
contact sensitivity to thiosalicilic acid", J. Am. Acad. Dermatol. 23, 479 (1990).
51. M. Alvaro, V. Baldoví, H. García, M. A. Miranda, J. Primo
"Influence of the b-substitution on the photochemistry of a,2-diacetoxystyrenes. Irradiation of
phenyl, vinyl and benzyl derivatives" Monatsh. Chem. 121, 267
(1990).
52.
L.
Fillol, M. A. Miranda, I. M. Morera, H. Sheikh "Photochemistry of 2(3H)
and 2(5H)-furanones", Heterocycles
31, 751 (1990).
53. G. Asensio, M. A. Miranda, J. Pérez-Prieto, M. J. Sabater, A.
Simón-Fuentes "Isomerization versus decarboxylation of protonated
oxetanone: comparison between experimental results and theoretical
calculations", Angew. Chem., Int. Ed. Engl. 29, 1146 (1990).
54.
F.
Boscá, M. A. Miranda, L. Vañó, F. Vargas "New
photodegradation pathways of Naproxen, a phototoxic nonsteroidal
antiinflammatory drug", J.
Photochem. Photobiol., A Chem. 54, 131 (1990).
55. M. A. Miranda, F. Vargas, G. Serrano "Photodegradation of Piroxicam
under aerobic conditions. The photochemical keys of the Piroxicam
enigma?", J. Photochem. Photobiol.,
B Biol 8, 199 (1991).
56. M. A. Miranda, I. M. Morera, F. Vargas, M. J. Gómez-Lechón,
J. V. Castell "In vitro assessment of the phototoxicity of
antiinflammatory 2-arylpropionic acids", Toxicol. in vitro 5, 451
(1991).
57. M. J. Climent, A. Corma, H. García, M. A. Miranda, J. Primo
"Photolysis of 4-acetoxychromene adsorbed on a Fe+3-exchanged
sepiolite", J. Photochem.
Photobiol., A Chem. 59, 379
(1991).
58. M. A. Miranda, J. Primo, R. Tormos "A new synthesis of Precocene II
and Precocene III based on the photo-Fries rearrangement of a sesamol
ester" Heterocycles 32, 1159 (1991).
59. H. García,
S. Iborra, M. A. Miranda, I. M. Morera, J. Primo "Pyrazoles and isoxazoles
derived from 2-hydroxyaryl phenylethynyl ketones: synthesis and
spectrophotometric evaluation of their potential applicability as sunscreens"
Heterocycles 32, 1745 (1991).
60. M. J. Climent, H. García, S. Iborra, M. A. Miranda, J. Primo
"Photolysis of cyclic enol esters in the presence and absence of a single
electron transfer photosensitizer" Tetrahedron
47, 9289 (1991).
61. F. Vargas, C. Rivas, M. A. Miranda, F. Boscá "Photochemistry
of non-steroidal anti-inflammatory drugs, propionic acid-derived", Pharmazie 46, 767 (1991).
62. F. Vargas, C. Rivas, R. Machado, M. A. Miranda "Photodegradation of
Nalidixic and Tiaprofenic acid and Nifedipine in aerobic conditions" Photodermatol. Photoimmunol. Photomed. 8, 218 (1991).
63.
F. Boscá, M. A. Miranda, F. Vargas
"Photochemistry of Tiaprofenic acid, a nonsteroidal antiinflammatory drug
with phototoxic side-effects", J.
Pharm. Sci. 81, 181 (1992).
64. F. Boscá, R. Martínez-Máñez, M. A. Miranda,
J. Primo, J. Soto, L. Vañó "Oxidative decarboxylation of
Naproxen", J. Pharm. Sci. 81, 479 (1992).
65. M. A. Miranda, H. García "Rearrangements" in "The
Chemistry of Functional Groups", Suppl. B 2 "The Chemistry of Acid
Derivatives", Edited by S. Patai, John Wiley & Sons, Chichester, 1992,
pp. 1271-1394.
66. V.
Baldoví, A. Corma, H. García, S. Iborra, M. A. Miranda, J. Primo
"Dual behaviour of sepiolites as electron acceptors or Lewis acids:
Reactivity of two acetoxystyrenes adsorbed on a Fe+3-exchanged sepiolite",
Recl. Trav. Chim. Pays Bas 111, 126 (1992).
67. J. V. Castell, M.
J. Gómez-Lechón, M. A. Miranda, I. M. Morera "Phototoxicity
of non-steroidal antiinflammatory drugs: in vitro testing of the photoproducts
of Butibufen and Flurbiprofen" J.
Photochem. Photobiol., B Biol. 13,
71 (1992).
68. M. Alvaro, H. García, M. A. Miranda, J. Primo "Preparation
and photolysis of diaryl esters of acetylenedicarboxylic acid", Tetrahedron 48, 3437 (1992).
69.
G. Asensio, J. Pérez-Prieto, M. C. Rams, M. A.
Miranda, M. J. Sabater "Direct observation and thermal transformations of
dications derived from dibenzotropylium ions", Tetrahedron 48, 8465
(1992).
70. G. Serrano, J. M. Fortea, J. M. Latasa, F. Millán, C.
Janés, F. Boscá, M. A. Miranda "Photosensitivity induced by
Fibric acid derivatives and its relation to photocontact dermatitis to
Ketoprofen", J. Am. Acad. Dermatol.
27, 204 (1992).
71. G. Asensio, M. A. Miranda, J. Pérez-Prieto, M. J. Sabater, A.
Simón-Fuentes "C5H9O2+ Ions: The correlation between their
thermochemistry in acidic solution and their chemistry in the gas phase", J. Org. Chem. 57, 6202 (1992).
72. M. A. Miranda "Phototoxicity of drugs" in "In vitro
alternatives to animal pharmaco-toxicology", Edited by J. V. Castell and
M. J. Gómez-Lechón, Farmaindustria, Madrid, 1992, pp. 239-270.
73. G. Serrano, J. M. Fortea, J. M. Latasa, O.
Sanmartín, J. Bonillo, M. A. Miranda "Oxicam-induced
photosensitivity. Patch and photopatch testing studies with
Tenoxicam and Piroxicam photoproducts in normal patients and in
Piroxicam-Droxicam photosensitive patients", J. Am. Acad. Dermatol. 26,
545 (1992).
74. F. Algarra, M. V. Baldoví, H. García, M. A. Miranda, J.
Primo "Direct photolysis and electron transfer photooxygenation of enol
acetates of 3-phenylpropiophenones", Monatsh.
Chem. 124, 209 (1993).
75. A. Corma, H. García, S. Iborra, V. Martí, M. A. Miranda, J.
Primo "Cooperative effect of acid sites in the photocyclization of
azobenzene within the zeolite microenvironment", J. Am. Chem. Soc. 115,
2177 (1993).
76. J. V. Castell, M.
J. Gómez-Lechón, C. Grassa, L. A. Martínez, M. A. Miranda,
P. Tárrega "Involvement of drug-derived peroxides in the
phototoxicity of Naproxen and Tiaprofenic acid", Photochem. Photobiol. 57,
486 (1993).
77. M. A. Miranda, R. Tormos " Photochemistry of o-allylphenol.
Identification of the minor products and new mechanistic proposals", J. Org. Chem. 58, 3304 (1993).
78. M. Alvaro, A. Corma, H. García, M. A. Miranda, J. Primo
"Photolysis of benzyl chloride included in NaY zeolite: product study
evidence for the implication of benzyl cation", J. Chem. Soc., Chem. Commun., 1041 (1993).
79. M. A. Miranda, J. V. Castell, M. J. Gómez-Lechón, L. A.
Martínez "In vitro photoperoxidation as an indicator of the
potential phototoxicity of non-steroidal anti-inflammatory 2-arylpropionic
acids", Toxicol. in vitro 7, 523 (1993).
80. M. Pitarch-Vinuesa, M. A. Miranda, M. Medio-Simón, J.
Sepúlveda-Arqués "Electron transfer reactions of
1-phenyl-4-vinylpyrazole mediated by cerium(iv) ammonium nitrate", Monatsh. Chem. 124, 959 (1993).
81. F. Algarra, M. V. Baldoví, H. García, M. A. Miranda, J.
Primo "Photorearrangement and electron transfer photooxidation of
1-acetoxy-1,2-diphenylcyclopropane", Tetrahedron
49, 10897 (1993).
82. F. Algarra, M. A. Miranda "Application of the photo-Fries
rearrangement of aryl N-chloroacetylanthranylates as key step in the synthesis
of 5-(2-hydroxyphenyl)-1,3-dihydro-2H-1,4-benzodiazepin-2-ones", Heterocycles 36, 2335 (1993).
83. F. Vargas, N. Canudas, M. A. Miranda, F. Boscá
"Photodegradation and in vitro phototoxicity of Fenofibrate, a
photosensitizing anti-hyperproteinemic drug", Photochem. Photobiol. 58,
471 (1993).
84. F. Vargas, N. Canudas, M. A. Miranda, F. Boscá "In vitro
phototoxicity of Clofibrate. Photochemical and photohemolytic studies on its
metabolite Clofibric acid", J.
Photochem. Photobiol., B Biol. 21
, 61 (1993).
85. A. Corma, H. García, M. A. Miranda, J. Primo, M. J. Sabater
"Modification of the photochemical reactivity of cyclic ethylene acetal of
a-bromopropiophenone by adsorption within zeolites. A combined contribution of
Lewis acidity and cage effect in the formation of a 2-phenylpropanoate via
1,2-phenyl shift", J. Org. Chem.
58, 6892 (1993).
86. J. V. Castell, L.
A. Martínez, M. A. Miranda, P. Tárrega "A general procedure
for isotopic (deuterium) labelling of non-steroidal antiinflammatory
2-arylpropionic acids", J. Labelled
Compd. Radiopharm. 35, 94
(1994).
87. M. A. Miranda, F. Boscá, F. Vargas, N. Canudas "Unusual (1,2)
Wittig rearrangement of a carbanion generated in neutral aqueous medium by
photodecarboxylation of a phenoxyacetic acid analogue", J. Photochem. Photobiol., A Chem. 78, 149 (1994).
88. J. V. Castell, M.
J. Gómez-Lechón, C. Grassa, L. A. Martínez, M. A. Miranda,
P. Tárrega "Photodynamic lipid peroxidation by the photosensitizing
nonsteroidal antiinflammatory drugs Suprofen and Tiaprofenic acid", Photochem. Photobiol.. 59, 35 (1994).
89. M. C. Jiménez, F. Márquez, M. A. Miranda, R. Tormos
"Photochemistry of o-allylphenol derivatives. Role of the phenolic and
styrenic excited states in the behavior of bichromophoric cinnamylphenol",
J. Org. Chem. 59, 107 (1994).
90. M. A. Miranda, F. Boscá, F. Vargas, N. Canudas
"Photosensitization by Fenofibrate. II. In vitro phototoxicity of the
major metabolites", Photochem.
Photobiol. 59, 171 (1994).
91. A. Corma, V. Fornés, H. García, M. A. Miranda, J. Primo, M.
J. Sabater "Photoinduced electron transfer within zeolite cavities: cis
stilbene isomerization photosensitized by 2,4,6-triphenylpyrylium cation
imprisoned inside zeolite Y", J. Am.
Chem. Soc. 116, 2276 (1994).
92. F. Rajadell, J. Planelles, F. Tomás, G. Asensio, M. A. Miranda, M.
J. Sabater "Competition between decarboxylation and isomerization in the
C3H5O2+ energy surface. Justification of the experimental results by molecular
orbital calculations on the solvated ions", J. Phys. Org. Chem. 7,
221 (1994).
93. W. Adam, M. A.
Miranda, F. Mojarrad, H. Sheikh "Carbon-carbon bond cleavage of the
[2.2]-p-cyclophane radical cation generated by electron transfer oxidation with
cerium(iv) ammonium nitrate (CAN)", Chem.
Ber. 127, 875 (1994).
94. M. A. Miranda, H. García "2,4,6-Triphenylpyrylium
tetrafluoroborate as an electron transfer photosensitizer", Chem. Rev. 94, 1063 (1994).
95. M. C. Jiménez, M. A. Miranda, J. Soto, R. Tormos "Electron
transfer oxidation of enol derivatives of 2,3-dihydrobenzopyran-4-ones", Tetrahedron 50, 7635 (1994).
96. F. Boscá, M. A. Miranda, G. Carganico, D. Mauleón
"Photochemical and photobiological properties of ketoprofen associated
with the benzophenone chromophore", Photochem.
Photobiol. 60, 96 (1994).
97. A. Moysan, M. A. Miranda, P. Morliere, L. Peno-Mazzarino, D. Averbeck, S.
Averbeck, P. Clement-Lacroix, L. Michel, M. Bazin, M. Geze, R. Santus, M.
Jeanmougin, J. V. Castell, L. Dubertret "Evaluation of phototoxicity: from
in vitro to in vivo", in "In vitro skin toxicology (methods in
irritation, phototoxicity and sensitization)", Edited by A. Rougier, A. M.
Goldberg and H. I. Maibach, pp. 185-194, M. A. Liebert Inc. (1994).
98. H. García,
M. A. Miranda, F. Mojarrad, M. J. Sabater "Involvement of oxirane
intermediates in the electron transfer-photooxygenation of 1,1- and
1,2-diarylethylenes sensitized by 2,4,6-triphenylpyrylium tetrafluoroborate",
Tetrahedron 50,
8773 (1994).
99. A. Corma, V. Fornés, H. García, M. A. Miranda, M. J.
Sabater "Extralarge pore aluminosilicates as suitable hosts to perform
highly efficient photoinduced electron transfer reactions with
2,4,6-triphenylpyrylium cation ", J.
Am. Chem. Soc. 116, 9767 (1994).
100. J. V. Castell,
M. J. Gómez-Lechón, D. Hernández, L. A. Martínez,
M. A. Miranda "Molecular bases of drug phototoxicity: photosensitized
damage by the major photoproduct of tiaprofenic acid", Photochem. Photobiol. 60, 586 (1994).
101. H. Spielmann, W.
W. Lovell, E. Hölzle, B. E. Johnson, T. Maurer, M. A. Miranda, W. J. W.
Pape, O. Sappora, D. Sladowski "In vitro phototoxicity testing. The report
and recommendations of ECVAM Workshop-2", ATLA, Alternatives to Laboratory Animals 22,
314 (1994).
102. M. C. Jiménez, M. A. Miranda, R. Tormos "Influence of the
intrazeolite microenvironment on the fate of the radical pairs formed by
photolysis of 3-bromo-4-chromanone", J.
Photochem. Photobiol., A: Chem. 86,
225 (1995).
103. M. A. Miranda "Photo-Fries reaction and related processes" in
"Handbook of Organic Photochemistry and Photobiology", Edited by W.
M. Horspool and P. S. Song, CRC Press, 1995, p. 570.
104. M. C. Jiménez, P. Leal, M. A. Miranda, R. Tormos "Chemical evidence
for intramolecular proton, electron and energy transfer in the photochemistry
of o-allylphenol derivatives", J.
Org. Chem. 60, 3243 (1995).
105. M. C. Jiménez, M. A. Miranda, R. Tormos "Photodecarboxylation
of 2-phenylpropionic acid in solution and included within b-cyclodextrin",
Tetrahedron 51, 2953 (1995).
106. M. A. Miranda, J. V. Castell, M. J. Gómez-Lechón, D.
Hernández, L. A. Martínez "Photobinding of drugs to cells as
an indicator of potential photoallergy", Toxicol. in vitro 9, 499
(1995).
107. M. C. Jiménez, M. A. Miranda, R. Tormos "Formation of
dichloromethyl phenyl ethers as major products in the photo-Reimer-Tiemann
reaction without base", Tetrahedron 51,
5825 (1995).
108. J. T. Banks, H.
García, M. A. Miranda, J. Pérez-Prieto, J. C. Scaiano "Laser
flash, laser drop and preparative photochemistry of
1,5-diiodo-1,5-diphenylpentane. Detection of a hypervalent iodine radical
intermediate", J. Am. Chem. Soc. 117, 5049 (1995).
109. F. Boscá, J. V. Castell, G. Carganico, L. A. Martínez, D.
Mauleón, M. A. Miranda "Evaluation of ketoprofen (R, S and R/S)
phototoxicity by a battery of in vitro assays", J. Photochem. Photobiol, B: Biol. 31, 133 (1995).
110. C. Barberá, H. García, M. A.
Miranda, J. Primo " Fotoquímica de p-toluididas de ácidos
a,b-insaturados. Influencia de la adición de carbonato
potásico", An. Quim. 91, 95 (1995).
111. J. F.
Ballesteros, M. J. Sanz, A. Ubeda, M. A. Miranda, S. Iborra, M. Payá, M.
J. Alcaraz "Synthesis and pharmacological evaluation of 2-hydroxychalcones
and flavones as inhibitors of inflammatory mediators generation", J. Med. Chem. 38, 2794 (1995).
112. M. C. Jiménez, P. Leal, M. A. Miranda, R. Tormos "Norrish
type I photoreaction of ketones in the presence of phenols. The intermolecular
version of photo-Fries rearrangement", J.
Chem. Soc., Chem. Commun. 2009 (1995).
113. A. Corma, V. Fornés, H. García, V. Martí, M. A.
Miranda "Acid zeolites as electron acceptors. Use of thianthrene radical
cation as a probe", Chem. Materials
7, 2136 (1995)
114. M. L. Cano, V. Fornés, H. García, M. A. Miranda, J.
Pérez-Prieto " Characterization of persistent a,v-diphenyl
substituted allyl cations within monodirectional acid zeolites", J. Chem. Soc., Chem. Commun. 2477
(1995).
115. M. V. Baldoví, H. García, M. A. Miranda, J. Primo, J. Soto,
F. Vargas "Modification of the photochemical reactivity of
a,b-diacetoxystilbene by adsorption onto a Fe+3 doped sepiolite: comparison
with the direct and 2,4,6-triphenylpyrylium-sensitized photolyses", Tetrahedron 51,
8113 (1995).
116. W. Adam, A. Corma,
M. A. Miranda, M. J. Sabater, C. Sahin "Photochemical (PET) and chemical
(CET) electron transfer reactions of 2,3-diazabicyclo[2.2.1]hept-2-enes
(azoalkanes) and bicyclo[2.1.0]pentanes (housanes) in solution and in zeolite
cavities", J. Am. Chem. Soc. 118, 2380 (1996).
117. N. Canudas, F.
Vargas, M. A. Miranda "Photodegradation of bezafibrate in aqueous media.
Studies on its in vitro phototoxicity", Arzneim. Forsch./Drug Research, 46, 694 (1996).
118. J. Perez-Prieto,
M. A. Miranda, H. García, K. Konya, J. C. Scaiano "Lamp versus
laser photolysis of a bichromophoric dichloroalkane. Chemical evidence for the
biphotonic generation of the 1,5-diphenylpentadiyl diradical", J. Org. Chem. 61, 3773 (1996).
119. M. L. Cano, A. Corma, V. Fornés, H. García, M. A. Miranda
"Triarylmethylium cations encapsulated within zeolites: A new class of
heterogeneous photosensitizers", J.
Am. Chem. Soc., 118, 11006
(1996).
120. M. J. Climent, M. A. Miranda "Gas chromatographic-mass spectrometric
study of photodegradation of carbamate pesticides" J. Chromatogr. A. 738,
225 (1996).
121. J.
Pérez-Prieto, M. A. Miranda, E. Font-Sanchis, K. Konya, J. C. Scaiano
"Lamp versus laser photolysis of 1,3-dichloro-1,3-diphenylpropane in
cyclohexane. Direct observation of 1,3-diphenylpropenyl radical", Tetrahedron Lett. 37, 4923 (1996)
122. P.
Gaviña, N. Lopez-Lavernia, R. Mestres, M. A. Miranda
"Deacetalization by photoinduced electron transfer with a pyrylium salt.
Effect of limiting the amounts of water, oxygen and sensitizer", Tetrahedron 52,
4911 (1996)
123. M. C. Jiménez, M. A. Miranda, R. Tormos "Photolysis of
3-bromochroman-4-ones", Heterocycles
43, 339 (1996)
124. F. Galindo, M. C. Jiménez, M. A. Miranda, R. Tormos
"Photochemical ortho-acylation of phenols with 1,1,1-trichloroethane",
J. Photochem. Photobiol., A:Chem., 97, 151 (1996)
125. V.
Fornés, H. García, M. A. Miranda, F. Mojarrad, M. J. Sabater, N.
N. E. Suliman, "Zeolite based heterogeneous photosensitizers containing
triphenylpyrylium and dibenzotropylium cations. Modifications of the product
selectivity in the cyclodimerization of 1,3-cyclohexadiene" Tetrahedron 52,
7755 (1996)
126. M. A. Miranda "Phototoxicity of Drugs" in "In vitro
Methods in Parmaceutical Research", Eds. J. V. Castell and M. J.
Gómez-Lechón, Academic Press, London, 1997, Capter 13, pp.
289-315.
127. J. Delgado, A.
Espinós, M. C. Jiménez, M. A. Miranda, R. Tormos "
2,4,6-Triphenylpyrylium tetrafluoroborate-photosensitized reactions of
o-cinnamylphenols and o-hydroxystilbenes", Tetrahedron 53, 681 (1997).
128. M. C. Jiménez, M. A. Miranda, R. Tormos "Photochemistry of
naproxen in the presence of cyclodextrin", J. Photochem. Photobiol., A: Chem. 104, 119 (1997).
129. M. J. Climent, M. A. Miranda "Photodegradation of dichlorprop and
2-naphthoxyacetic acid in water. Combined GC-MS and GC-FTIR study", J. Agr. Food Chem. 45, 1916 (1997).
130. F. Boscá, S. Encinas, P. F. Heelis, M. A. Miranda
"Photophysical and photochemical characterization of a photosensitizing
drug. A combined steady state photolysis and laser flash photolysis study on
carprofen", Chem. Res. Toxicol. 10, 820 (1997).
131. M. A. Miranda "Assessment of the phototoxicity risk of new
drugs", Arch. Toxicol. S19, 249 (1997).
132. M. A. Miranda, J. Pérez-Prieto, E. font-Sanchis, K. Kónya,
J. C. Scaiano "Laser flash, laser drop and lamp photolysis on
1,3-dichloro-1,3-diphenylpropane. One- versus two-photon reaction
pathways", J. Org. Chem. 62, 5713 (1997).
133. M. C. Jiménez, M. A. Miranda, J. C. Scaiano, R. Tormos
"Two-photon processes in the photo-Claisen and photo-Fries rearrangements.
Direct observation of dienic ketenes generated by photolysis of transient
cyclohexa-2,4-dienones", Chem.
Commun. 1487 (1997).
134. D. de la Peña, C.
Martí, S. Nonell, L. A. Martínez, M. A. Miranda
"Time-resolved near infrared studies on singlet oxygen production by the
photosensitizing 2-arylpropionic acids", Photochem. Photobiol 65,
828 (1997).
135. M. A. Miranda, J. V. Castell, M. J. Gómez-Lechón, D.
Hernández, I. M. Morera, I. Puertas, Z. Sarabia "Mechanisms of
photosensitization by drugs: involvement of tyrosines in the photomodification
of proteins mediated by tiaprofenic acid in vitro", Toxicol. in vitro 11,
653 (1997).
136. A. Abad, J. J. Manclús, F. Mojarrad, J. V. Mercader, M. A.
Miranda, J. Primo, V. Guardiola, A. Montoya "Hapten synthesis and
production of monoclonal antibodies to DDT and related compounds", J. Agr. Food Chem. 45, 3694 (1997).
137. M. C. Jiménez, M. A. Miranda, R. Tormos "Photocyclization of
2-cinnamylphenols via excited state proton transfer (ESPT) involving the
lowest-lying styrene singlet", Tetrahedron
53, 14729 (1997).
138. H. de Vries, S.
Encinas, M. A. Miranda, J. V. Castell, G. M. J. Beijersbergen van Henegouwen
"Photodegradation and photobinding of tiaprofenic acid: in vitro versus in
vivo", Photochem. Photobiol. 66,
432 (1997).
139. P. Moya, M. Castillo, E.
Primo-Yúfera, F. Couillaud, R. Martínez-Máñez, M.
D. Garcerá, M. A. Miranda, J. Primo, R. Martínez-Pardo
"Brevioxime: a new juvenile hormone biosynthesis inhibitor isolated from Penicillium brevicompactum", J. Org. Chem. 62, 8544 (1997).
140. S. Encinas, M.
A. Miranda, S. Monti "Triple photoreactivity of the diaryl ketone
tiaprofenic acid and its decarboxylated photoproducts. Photobiological
implications", Photochem. Photobiol.
67, 420 (1998).
141. M. A. Miranda, J. V. Castell, Z. Sarabia, D. Hernández, M. J.
Gómez-Lechón, I. M. Morera "Drug-photosensitized protein
modification: identification of the reactive sites and elucidation of the
reaction mechanism with tiaprofenic acid/albumin as model system", Chem. Res. Toxicol. 11, 172 (1998).
142. F. Galindo, M. A. Miranda " Pyrylium and thiopyrylium salts as
electron transfer photosensitizers for the (2p+2p) cyclodimerization of
poly(vinyl cinnamate) in solution", J.
Photochem. Photobiol., A: Chem. 113, 155 (1998).
143. M. C. Jiménez, M. A. Miranda, R. Tormos "Competition between
cyclization and dehalogenation in the photochemistry of cinnamylphenols with
halogen substituents at the phenolic and styrenic chromophores", J. Org. Chem. 63, 1323 (1998).
144. M. C. Jiménez, P. Leal, M. A. Miranda, J. C. Scaiano, R. Tormos
"Photocyclization of cinnamylnaphthols", Tetrahedron 54, 4337
(1998).
145. F. Boscá, M. A. Miranda "Photosensitizing drugs containing
the benzophenone chromophore (Invited Review)", J. Photochem. Photobiol., B: Biol. 43, 1 (1998).
146. M. A. Miranda, J. Pérez-Prieto, E. Font-Sanchis, K. Kónya,
J. C. Scaiano "Flash photolysis of 1,3-dichloro-1,3-diphenylpropane in
polar solvents. Generation of a stabilized g-chloropropyl cation, subsequent formation of a propenyl cation and
nucleophilic trapping of both cations", J. Phys. Chem. 102, 5724
(1998)..
147. F. Boscá, M. A. Miranda, G. Serrano, F. Vargas
"Photochemistry and photobiological properties of dicloran, a post-harvest
fungicide with photosensitizing side-effects", Photochem. Photobiol. 67,
532 (1998).
148. S. Encinas, M.
A. Miranda, S. Monti "Transient species in the photochemistry of tiaprofenic
acid and its decarboxylated photoproduct", Photochem. Photobiol. 68,
633 (1998).
149. M. C. Terencio, I. Guillén, M. J. Gómez-Lechón, M.
A. Miranda, J. V. Castell "Release of inflammatory mediators (PGE2, IL-6)
by fenofibric acid-photosensitized human keratinocytes and fibroblasts", Photochem. Photobiol. 68, 331 (1998).
150. M. A. Miranda, J. Pérez-Prieto, E. Font-Sanchis, J. C. Scaiano
"Mechanistic studies on the photogeneration of o- and p- xylylenes from
alpha,alpha-dichloroxylenes", Chem.
Comm., 1541 (1998).
151. S. Encinas, F.
Boscá, M. A. Miranda "Phototoxicity associated with diclofenac: a
photophysical, photochemical and photobiological study on the drug and its
photoproducts", Chem. Res. Toxicol.
11, 946 (1998).
152. F. Galindo, M. A. Miranda, R. Tormos "Coupling of phenoxy and alkyl
radicals derived from the photolysis of phenol/ketone pairs: an intermolecular
approach to the photo-Claisen rearrangement", J. Photochem. Photobiol., A:Chem. 117, 17 (1998).
153. M. T. Bosch, L. Domingo, M. C. Jiménez, M. A. Miranda, R. Tormos
"Ground and excited state intramolecular interaction in phenol/olefin
bichromophoric compounds", J. Chem.
Soc., Perkin Trans. 2, 2175 (1998)
154. S. Monti, S.
Sortino, S. Encinas, G. Marconi, G. de Guidi and M. A. Miranda "Photoprocesses
in photosensitizing drugs containing a benzophenone-like chromophore", in Drugs: Photochemistry and Photostability,
edited by E. Fasani and A. Albini, The Royal Society of Chemistry, Cambridge,
pp. 150-161 (1998).
155. S. Encinas, F.
Boscá, M. A. Miranda "Photochemistry of 2,6-dichlorodiphenylamine
and 1-chlorocarbazole, the photoactive chromophores of diclofenac, meclofenamic
acid and their major photoproducts", Photochem.
Photobiol. 68, 640 (1998).
156. J. V. Castell,
M. J. Gómez-Lechón, D. Hernández, A. Lahoz, M. A. Miranda,
I. M. Morera, J. Pérez-Prieto, Z. Sarabia "Photobinding of
tiaprofenic acid and suprofen to proteins and cells: A combined study using
radiolabeling, antibodies and laser flash photolysis of model bichromohores",
Photochem. Photobiol. 68, 660 (1998).
157. P. Moya, A.
Cantín, M. A. Castillo, M. A. Miranda, J. Primo, E. Primo-Yúfera
"Isolation, structural asignment and synthesis of
N-(2-methyl-3-oxodecanoyl)-2-pyrroline, a new natural product from Penicillium brevicompactum with in vitro anti-juvenile hormone
activity", J. Org. Chem. 63, 8530 (1998).
158. A. Cantín, P. Moya, M. A. Miranda, J. Primo, E.
Primo-Yúfera "Isolation of N-(2-methyl-3-oxodecanoyl)pyrrole and
N-(2-methyl-3-oxodec-8-enoyl)pyrrole, two new natural products from Penicillium brevicompactum and synthesis
of analogues with insecticidal and fungicidal activity", J. Agr. Food Chem. 46, 4748 (1998).
159. M. A. Miranda, J. Pérez-Prieto, E. Font-Sanchis, K. Kónya,
J. C. Scaiano "A four-membered ring hypervalent iodine radical", J. Phys. Chem.102, 9975 (1998).
160. M. A. Miranda, Z. Sarabia, D.
Hernández, I. M. Morera, M. J. Gómez-Lechón, J. V.
Castell. "An in vitro approach to drug
photoallergy: Use of drug-directed antibodies to assess photobinding of
non-steroidal anti-inflammatories to skin cells". Toxicol. in vitro 13,
701 (1999).
161. M. A. Miranda, J. Pérez-Prieto, A.
Lahoz, I. M. Morera, Z. Sarabia, R. Martínez-Máñez, J. V.
Castell. "Isolation of cross-coupling products in
model studies on the photochemical modification of proteins by tiaprofenic
acid". Eur. J.
Org. Chem., 497 (1999).
162. P. Moya, A. Cantín, M. A.
Miranda, J. Primo, E. Primo-Yúfera. "Synthesis
and biological evaluation of new analogues of the active fungal metabolites
N-(2-methyl-3-oxodecanoyl)-2-pyrroline and
N-(2-methyl-3-oxodec-enoyl)-2-pyrroline". J. Agr. Food Chem. 47,
3866 (1999).
163. M. A. Castillo, P. Moya, A. Cantín, M. A. Miranda, J. Primo, E.
Hernández, E. Primo-Yúfera."Insecticidal, antijuvenile
hormone and fungicidal activity of organic extracts from different Penicillium
species and their isolated active compounds". J. Agr. Food Chem. 47,
2120 (1999).
164. M. A.
Miranda, E. Font-Sanchis, J. Pérez-Prieto. "Photochemisty
of acyl-alkyl biradicals". J. Org.
Chem. 64, 3802 (1999).
165. A. Cantín, P. Moya, M. A. Castillo, J.
Primo, M. A. Miranda, E. Primo-Yúfera. "Isolation
and synthesis of N-(2-methyl-3-oxodec-8-enoyl)-2-pyrroline and
2-(hept-5-enyl)-3-methyl-4-oxo-6,7,8,8a-tetrahydro-4H-pyrrolo(2,1-b)-3-oxazine,
two new fungal metabolites with in vivo antijuvenile hormone and insecticidal
activity". Eur. J. Org. Chem. 221 (1999).
166. A. M.
Amat, A. Arques, M. A. Miranda. "p-Coumaric acid
photodegradation with solar light, using a 2,4,6-triphenylpyrylium salt as
photosensitizer". Appl. Catal., B: Environmental 23, 205 (1999).
167. M. A.
Miranda, E. Font-Sanchis, J. Pérez-Prieto, J. C. Scaiano. "Two-photon generation of the 1,4-diphenyl-1,4-butanediyl
biradical: direct detection and product studies". J. Org. Chem. 64, 7842
(1999).
168. G. Ouedraogo, P. Morlière, M. Bazin, R. Santus, B. Kratzer, M. A.
Miranda, J. V. Castell. "Lysosomes are sites of fluoroquinolone
photosensitization in human skin fibroblasts: a microspectrofluorometric
approach". Photochem. Photobiol.
70, 123 (1999).
169. M. A. Miranda, A. Lahoz, R. Martínez-Máñez, F.
Boscá, J. V. Castell, J. Pérez-Prieto. "Enantioselective
discrimination in the intramolecular quenching of an excited state aromatic
ketone by a ground state phenol". J.
Am. Chem. Soc., 121, 11569
(1999).
170. M. A.
Miranda, E. Font-Sanchis, J. Pérez-Prieto, J. C. Scaiano. "Five-membered ring 9-I-2 radicals: direct detection and comparison
with other hypervalent iodine radicals". Org. Lett.1, 1587 (1999).
171. F.
Boscá, M. A. Miranda. "A laser flash
photolysis study on fenofibric acid".
Photochem. Photobiol. 70 , 853 (1999).
172. J. Delgado, A. Espinós, M. C.
Jiménez, M. A. Miranda, H. D. Roth, R. Tormos. “Photoreactions
of trans-1-o-hydroxyphenyl-2-phenylcyclopropane”, J. Org. Chem. 64, 6541 (1999).
173.
F. Boscá, N. Canudas, M. L. Marín, M. A. Miranda. “A photophysical and photochemical study on 6-methoxy-2-naphthylacetic
acid, the major metabolite of the phototoxic NSAID nabumetone". Photochem. Photobiol. 71, 173 (2000).
174. C.
Agapakis-Caussé, F. Boscá, J. V. Castell, D. Hernández, M.
L. Marín, L. Marrot, M. A. Miranda. “Tiaprofenic acid-photosensitized
damage to nucleic acids: A mechanistic study using complementary in vitro
approaches”. Photochem. Photobiol. 71, 499 (2000).
175. F. Boscá, M. A.
Miranda, I. M. Morera, A. Samadi. “Involvement of Type I and Type II mechanisms
in the linoleic acid peroxidation photosensitized by tiaprofenic acid”. J. Photochem. Photobiol., B: Biol. 58, 1 (2000).
176. J. Moser, F. Boscá, W. W. Lovell,
J. V. Castell, M. A. Miranda, A. Hye. “Photobinding of carprofen to protein”. J. Photochem. Photobiol., B: Biol. 58, 13 (2000).
177. M. D. Barratt, J. V. Castell, M.
A. Miranda, J. J. Langowski. “Development of an expert
system rulebase for the prospective identification of photoallergens”. J. Photochem. Photobiol., B: Biol. 58, 54 (2000).
178. G. Ouedraogo, P.
Morlière, R. Santus, M. A. Miranda, J. V. Castell. “Damage to mitochondria of cultured human skin fibroblasts
photosensitized by fluoroquinolones”. J.
Photochem. Photobiol., B: Biol. 58,
20 (2000).
179. M. Bazin, F.
Boscá, M. L. Marín, M. A. Miranda, L. K. Patterson, R. Santus. “A
laser flash photolysis and pulse radiolysis study of primary photochemical
processes of flumequine”. Photochem. Photobiol. 72, 451 (2000).
180. M. A. Miranda, F. Galindo, A. M.
Amat, A. Arques. “Pyrylium salt-photosensitized degradation of
phenolic contaminants derived from cinnamic acid with solar light. Correlation
of the observed reactivities with fluorescence quenching”. Appl.
Catal. B: Environmental 28, 127 (2000).
181. F. Galindo, M. C.
Jiménez, M. A. Miranda, R. Tormos. “Excited
state interactions in phenol/olefin bichromophric compounds. Direct detection
of an intramolecular exciplex”. Chem.
Commun. 1747 (2000).
182. A. Cantin, P. Moya, M.
A. Miranda, J. Primo, E. Primo-Yúfera. “Synthesis and biological
evaluation of new analogues of the active fungal metabolites
N-(2-methyl-3-oxodecanoyl)-2-pyrroline and
N-(2-methyl-3-oxodec-8-enoyl)-2-pyrroline (II)”. J. Agr. Food Chem. 48,
3682 (2000).
183. M. C. Jiménez,
M. A. Miranda, R. Tormos. “Di-p-methane photorearrangement of trans-1,3-diphenylpropene upon excitation
to higher singlet states in polar solvents”. Chem. Commun. 2341 (2000).
184. F. D. Lewis, X. B. Zuo, R. S.
Kalgutkar, M. A. Miranda, E. Font-Sanchis, J. Pérez-Prieto. “The di-p-methane reaction of
3,3-dimethyl-1,3-diphenylpropene revisited. Dynamics and barriers for
competitive singlet-state reactions”. J.
Am. Chem. Soc. 122, 8571 (2000).
185. M. E. Padilla-Tosta,
J. M. Lloris, R. Martínez-Máñez, A. Benito, J. Soto, T.
Pardo, M. A. Miranda, M. D. Marcos. “Bis(terpyridyl)ruthenium(II)
units attached to polyaza cycloalkanes as sensing fluorescent receptors for
transition metal ions”. Eur. J. Inorg. Chem. 741 (2000).
186. M. J. Climent, M. A.
Miranda, H. D. Roth. “Triphenylpyrylium tetrafluoroborate-sensitized
photochemistry of the terpenes sabinene, a-phellandrene
and a-terpinene and g-terpinene”. Eur. J.
Org. Chem. 1563 (2000).
187. G. Asensio, M. A.
Miranda, M. J. Sabater, J. Pérez-Prieto, A. Simón-Fuentes, R.
Mello. “C5H7O2+
Ions. The correlation between their thermochemistry in acidic solutions and
their chemistry in the gas phase”. J.
Org. Chem. 65, 964 (2000).
188. M.
A. Miranda, A. Lahoz, F. Boscá, M. R. Metni, F. B. Abdelouahab, J. V.
Castell, J. Pérez-Prieto. “Regio- and stereoselectivity in the
intramolecular quenching of the excited benzoylthiophene chromophore by
tryptophan”. Chem.
Commun. 2257 (2000).
189. B. Quintero, M. A. Miranda. “Mechanisms of photosensitization induced by drugs: A general survey”. Ars Pharmaceutica 41, 27
(2000).
190. M. A. Miranda, J.
Pérez-Prieto, E. Font-Sanchis, J. C. Scaiano. “One-
vs. two-photon processes in the photochemistry of 1,n-dihaloalkanes”, Acc. Chem. Res. 34, 717 (2001).
191. M. A. Miranda, F. Galindo, A. M.
Amat, A. Arques. “Pyrylium salt-photosensitized degradation of
phenolic contaminants present in olive oil wastewaters with solar light. Part
II. Benzoic acid derivatives”. Appl. Catal. B: Environmental 30, 437 (2001).
192. M. A. Miranda, E. Font-Sanchis,
J. Pérez-Prieto, J. C. Scaiano. “Photochemistry
of 1,n-diiodoalkanes”. Progr. React.
Kinet. Mech. 26, 139 (2001).
193. A. Samadi, L. A.
Martínez, M. A. Miranda, I. M. Morera. “Mechanism
of lipid peroxidation photosensitized by tiaprofenic acid: product studies
using linoleic acid and 1,4-cyclohexadienes as model substrates”. Photochem. Photobiol. 73, 359 (2001).
194. F. Boscá, M.
C. Cuquerella, M. L. Marín, M. A. Miranda. “Photochemistry of
2-hydroxy-4-trifluoromethylbenzoic acid, the major metabolite of the
photosensitizing platelet antiaggregant drug triflusal”. Photochem. Photobiol. 73,
463 (2001).
195. M. A. Miranda.
“Photosensitization by drugs”. Pure Appl. Chem. 73, 481 (2001).
196. M. A. Miranda, E. Font-Sanchis,
J. Pérez-Prieto, J. C. Scaiano. “The
4,4’-(1,2-ethanediyl)bisbenzyl biradical: its generation, detection and
(photo)chemical behavior in solution”. J.
Org. Chem. 66, 2717 (2001).
197. J. Moser, A. Hye, W. W. Lovell, L. K.
Earl, J. V. Castell, M. A. Miranda. “Mechanisms of drug photobinding to
proteins: photobinding of suprofen to human serum albumin”. Toxicol. In vitro 15, 333 (2001).
198. F. Boscá, M.
L. Marín, M. A. Miranda. “Photoreactivity of the
non-steroidal anti-inflammatory 2-arylpropionic acids with photosensitizing
side effects”. Photochem. Photobiol. 74, 637 (2001).
199. M. E. Padilla-Tosta,
J. M. Lloris, R. Martinez-Mañez, M. D. Marcos, M. A. Miranda, T. Pardo,
F. Sancenón, J. Soto. “Fluorescent chemosensors
for heavy metal ions based on bis ter(pyridyl) ruthenium (II) complexes
containing aza-oxa and polyaza macrocycles”. Eur. J. Inorg. Chem. 6, 1475 (2001).
200. A. Lahoz, D. Hernández,
M. A. Miranda, J. Pérez-Prieto, I. M. Morera, J. V. Castell. “Antibodies directed to drug epitopes
toinvestigate the structure of drug-protein photoadducts. Recognition of a
common photobound substructure in tiaprofenic acid/ketoprofen
cross-photoreactivity”. Chem. Res.
Toxicol. 14, 1486 (2001).
201. F. Sancenón, A. B.
Descalzo, R. Martínez-Máñez, M. A. Miranda, J. Soto “A
colorimetric ATP sensor based on 1,3,5-triarylpent-2-en-1,5-diones”. Angew.
Chem., Int. Ed. Engl. 40, 2640 (2001).
202. A. Cantín, C. Llull, J.
Primo, M. A. Miranda, E. Primo-Yúfera. “Isolation, structural assignment and insecticidal
activity of (1S,2R,3R,4S) 1,2-epoxy-1-methyl-4-(1-methyl)cyclohe-3-yl acetate,
a natural product from Minthostachys
tomentosa”- Tetrahedron Asymmetry
12, 677 (2001).
203. M. A. Miranda, M. A. Izquierdo,
F. Galindo. “Steady-state and
time-resolved studies on oxetane cycloreversion using (thia)pyrylium salts as
electron transfer photosensitizers”. Org. Lett. 3,
1965 (2001).
204. S. Monti, S. Encinas, A. Lahoz, G.
Marconi, S. Sortino, J. Pérez-Prieto, M. A. Miranda. “Structure and photochemical
behavior of the cyclodextrin inclusion
complexes of benzoylthiophene-derived drugs”. Helv. Chim. Acta 84, 2452 (2001).
205. M. A. Miranda, A. M. Amat, A. Arques. “Abatement of
the major contaminants present in olive oil industry wastewaters by different
oxidation methods: ozone and/or UV radiation vs. solar light”. Water Sci. Technol. 44, 325 (2001).
206. F. D. Lewis, X. Zuo,
R. S. Kalgutkar, J. M. Wagner-Brennan, M. A. Miranda, E. Font-Sanchis, J.
Perez-Prieto “Temperature-Dependent Photochemistry of
1,3-Diphenylpropenes. The di-p
Methane Reaction Revisited”. J. Am. Chem.
Soc. 123, 11883 (2001).
207. O. Benali, M. C. Jimenez, M. A. Miranda, R. Tormos. “Novel photohydration of non-conjugated ary/olefin bichromophores within
cyclodextrin cavities”, Chem. Commun.,
2328 (2001).
208. M. A. Miranda, M. L. Marín, A. M. Amat, A.
Arques, S. Seguí. “Pyrylium salt-photosensitized degradation of phenolic
contaminants present in olive oil wastewaters by solar light. Part III: Tyrosol
and p-hydroxyphenylacetic acid”. Appl. Catal. B: Environmental 35, 167
(2002).
209. M. C. Jimenez, M. A.
Miranda, R. Tormos. “Intramolecular excited state interaction in
phenol/styrene bichromophoric systems: a photochemical and photophysical
study”, Tetrahedron 58, 115 (2002).
210. M. C. Jiménez, M. A.
Miranda, R. Tormos, S. Gil. “Photocyclization
of a bichromophoric phenol/olefin system substituted at the methylene spacer:
chemical evidences for an excited state proton transfer involving an H-bridged
intermediate”. Eur. J. Org. Chem. 297 (2002).
211. M. A. Miranda, L. A.
Martínez, A. Samadi, F. Boscá, I. M. Morera. “Stereoselective
intramolecular hydrogen abstraction by a
chiral benzophenone derivative”. Chem.
Commun., 280 (2002).
212. G. Cosa, S. Purohit, J. C.
Scaiano, F. Boscá, M. A. Miranda. “A
laser flash photolysis study on fenofibric acid in aqueous buffered media:
unexpected triplet state inversion in a 4-methoxybenzophenone derived
compound”. Photochem. Photobiol. 75, 193 (2002).
213. M. A. Miranda, E. Font-Sanchis,
J. Pérez-Prieto, J. C. Scaiano. “Flash
photolysis of trans-1,2-bis-(1-chloro-1-phenylmethyl)cyclopropane. Generation
of 1,5-diphenylpentadienyl radical and 1,5-diphenylpentadienylium cation”. J. Org. Chem. 67, 1162 (2002).
214. S. Sortino, S. Petralia, F. Boscá, M. A. Miranda. “Irreversible photo-oxidation of propanolol triggered by self-photogenerated
singlet molecular oxygen”. Photochem.
Photobiol. Sci.1, 136 (2002).
215. U. Pischel, M. S. Galletero, H. García, M. A. Miranda, W.
M. Nau. “Photophysical properties and fluorescence
quenching of 2,3-diazabicyclo(2.2.2)oct-2-ene in zeolites: linear diffusion
provides an explanation for non-monoexponential transient decay kinetics”. Chem. Phys. Lett. 359, 289
(2002).
216. M. A. Miranda, M. A.
Izquierdo, F. Galindo. “Involvement of triplet
excited states and olefin radical cations in electron-transfer cycloreversion
of four-membered ring compounds photosensitized by (thia)pyrylium salts”. J. Org. Chem. 67, 4138 (2002).
217. M. A. Miranda, M. A.
Izquierdo. “Stepwise cycloreversion of oxetane radical
cations with initial C-O bond cleavage”. J.
Am. Chem. Soc. 124, 6532 (2002).
218. M. A. Miranda, A. M.
Amat, A. Arques. “Improved stability and performance of silica gel-supported
triphenylpyrylium cation as a heterogeneous photocatalyst for olive oil
wastewaters treatment”. Catal. Today 76, 113 (2002).
219. O. Benali, M. A. Miranda, R. Tormos. “Electron
transfer versus proton transfer in the excited state of bichromophoric
aniline/olefin systems”. Eur. J. Org. Chem. 2317 (2002).
220. F. Boscá, G. Cosa, M. A. Miranda, J. C.
Scaiano. “Inversion of 4-methoxybenzophenone triplet in
aqueous medium”. Photochem. Photobiol.
Sci. 1, 704 (2002).
221. E. Font-Sanchis, M. A. Miranda, J. Pérez-Prieto, J. C. Scaiano.
“Laser
Flash Photolysis of [3,n]Paracyclophan-2-ones. Direct
observation and chemical behavior of 4,4´-(1,n-alkanediyl)bisbenzyl
biradicals”. J. Org. Chem. 67, 6131 (2002).
222. A. Belvedere, F.
Bosca, M. C. Cuquerella, G. De Guidi, M. A. Miranda. "Photoinduced
N-demethylation of rufloxacin and its methyl ester under aerobic conditions”. Photochem. Photobiol. 76,
252 (2002).
223. A. Belvedere, F.
Bosca, A. Catalfo, M. C. Cuquerella, G. De Guidi, M. A. Miranda. "Type II guanine oxidation photoinduced by the antibacterial
fluoroquinolone rufloxacin in isolated DNA and in 2´-deoxyguanosine”. Chem. Res. Toxicol. 15, 1142
(2002).
224. O. Benali, M. A. Miranda, R. Tormos, S. Gil. “Entropy-controlled diastereoselectivity in the photocyclization of
rigid derivatives of o-allylaniline”. J.
Org. Chem. 67, 7915 (2002).
225. G. Cosa, L. Llauger,
J. C. Scaiano, M. A. Miranda. “Absolute rate constants for
water protonation of 1-(3-benzoylphenyl)alkyl carbanions”. Org. Lett. 4, 3083 (2002).
226. J. Delgado, A. Espinos, M. C. Jiménez, M. A. Miranda. “Novel generation of an o-quinone methide from 2-(2'-cyclohexenyl)phenol
by excited state intramolecular proton transfer and subsequent C-C
fragmentation”. Chem. Commun., 2636 (2002).
227. M. A. Miranda, F.
Galindo. “The photo-Fries rearrangement”. In Molecular and Supramolecular Photochemistry,
Vol. 9, Edited by V. Ramamurthy, Marcel Dekker, pp. 43-132 (2003).
228.. M. A. Miranda, M. A.
Izquierdo. “Chemical and transient
spectroscopic evidence for C2-C3 cleavage of
2,3-diaryloxetane radical cations”. Chem. Commun. 364 (2003).
229. F. Sancenon, R. Martinez-Manez, M. A. Miranda, M. J. Segui, J. Soto. “Towards the development of colorimetric
probes to discriminate between isomeric dicarboxylates”. Angew.
Chem., Int. Edit. 42,
647 (2003).
230. M. A. Miranda, M. A. Izquierdo, R. Perez-Ruiz. “Direct photophysical evidence for quenching of the
triplet excited state of 2,4,6-triphenyl(thia)pyrylium salts by
2,3-diaryloxetanes”. J. Phys. Chem. A
107, 2478 (2003).
231. U. Pischel, S. Abad, M. A. Miranda.
“Stereoselective fluorescence quenching by photoinduced electron transfer in
naphthalene-amine dyads”. Chem. Commun. 1088
(2003).
232. A. M. Amat, A. Arques, S. H.
Bossmann, A. M. Braun, S. Göb, M. A. Miranda. “A
camel through the eye of a needle: direct introduction of
2,4,6-triphenylpyrylium ion inside Y-zeolites by formal ion exchange in aqueous
medium”, Angew. Chem., Int. Ed. Engl. 42, 1653 (2003)..
233. M. C. Cuquerella, F. Bosca, M. A.
Miranda, A. Belvedere, A. Catalfo, G. de Guidi. “Photochemical properties of ofloxacin
involved in oxidative DNA damage: A comparison with rufloxacin”. Chem. Res.
Toxicol. 16, 562 (2003).
234. J. Perez-Prieto, F. Bosca, R. E. Galian,
A. Lahoz, L. R. Domingo, M. A. Miranda. “Photoreaction between 2-benzoylthiophene and phenol or indole”, J.
Org. Chem. 68, 5104 (2003).
235. V. Lhiaubet-Vallet, J. Trzcionka, S. Encinas, M.
A. Miranda, N. Chouini-Lalanne. “Photochemical and photophysical properties of
indoprofen”, Photochem. Photobiol. 77, 487 (2003).
236. F. Bosca, I. Andreu, I. M. Morera, A. Samadi, M. A.
Miranda. “Chiral discrimination in the intramolecular abstraction of allylic
hydrogens by benzophenone triplets”, Chem. Commun. 1592 (2003).
237. U. Pischel, S. Abad, L. R. Domingo, F.
Bosca, M. A. Miranda. “Diastereomeric
differentiation in the quenching of excited states by hydrogen donors”, Angew.
Chem., Int. Ed. 42, 2531 (2003).
238. A. M. Amat, A. Arques, H.
Beneyto, A. Garcia, M. A. Miranda, S. Segui. “Ozonization coupled with biological degradation for treatment of
phenolic pollutants: a mechanistically based study”, Chemosphere 53,
79 (2003).
239. R. Gonzalez-Luque, M. Merchan,
M. Rubio, L. Serrano-Andres, B. O. Roos, M. A. Miranda. “A theoretical analysis of the excited states in
2-benzoylthiophene”, Mol. Phys. 101, 1977 (2003).
240. M. A. Miranda, M. A. Izquierdo. “Photosensitiser-controlled regioselectivity in the
electron-transfer cycloreversion of 2,3-diphenyloxetanes”, Photochem.
Photobiol. Sci. 2, 848 (2003).
241. V. Lhiaubet-Vallet, Z. Sarabia, D. Hernandez, J. V. Castell, M. A.
Miranda. “In vitro studies on DNA-photosensitization by different drug
stereoisomers”, Toxicol. in Vitro 17, 651 (2003).
242. J. Perez-Prieto, R. E. Galian, M. C.
Morant-Minana, M. A. Miranda. “Steady-state
and time-resolved studies on the formation of skatolyl radicals photosensitized
by 2-benzoylthiophene”, Photochem. Photobiol. Sci. 2, 1200
(2003).
243. E.A. Leo; J. Delgado, L.R. Domingo, A. Espinos;
M.A. Miranda, R. Tormos, “Photogeneration of o-Quinone Methides from
o-Cycloalkenylphenol”. J.
Org. Chem., 68,
9643 (2003).
244.
R. Perez-Ruiz, M. A. Izquierdo, M. A. Miranda “Reductive PET cycloreversion of oxetanes:
singlet multiplicity, regioselectivity, and detection of olefin radical
anion”. J. Org. Chem. 68, 10103 (2003).
245. J.
Perez-Prieto, R. E. Galian, M.A., Miranda, F. Catalina; N. Martin-Vargas, F.
Lopez “Benzo[d]-1,2-oxaphospholes as precursors of stabilized C-centered
radicals”. Org. Lett. 6, 561 (2004).
246. M.C. Jimenez; S-E. Stiriba, R.Tormos, J. Perez-Prieto, M.A.
Miranda. “Stereoselectivity in the triplet decay of chiral
benzophenone-naphthalene bichromophoric systems”. Photochem. Photobiol. Sci 3, 36 (2004).
247. J. Perez-Prieto, A. Lahoz, F. Bosca, R.
Martinez-Manez, M.A. Miranda. “Stereodifferentiation in the decay
of triplets and biradicals involved in intramolecular hydrogen transfer from
phenols or indoles to p,p aromatic ketones”. J. Org. Chem, 69, 374 (2004).
248. F.
Bosca, M.L. Marin, M.A. Miranda. “Photodecarboxylation of acids and lactones:
antiinflammatory drugs”, en Handbook of Organic Photochemistry and
Photobiology (2nd Edition). Editor(s): Horspool, William; Lenci, Francesco.
CRC Press. Boca Raton pp 64/1-64/10 (2004).
249. M. A. Miranda, F. Galindo. “Photo-Fries
reaction and related processes”, en Handbook of Organic Photochemistry and
Photobiology (2nd Edition). Editor(s): Horspool, William; Lenci, Francesco.
CRC Press. Boca Raton, pp 42/1-42/11 (2004).
250. M. A. Izquierdo, M. A. Miranda
“Electron-transfer cycloreversion of 2,3-diaryloxetanes: influence of
the substitution and the photosensitizer on the regioselectivity”. Eur. J. Org. Chem., 1424 (2004).
251. J. J. Manclus, A. Abad, M. Y.
Lebedev, F. Mojarrad, B. Mickova, J. V. Mercader, J. Primo, M. A. Miranda, A.
Montoya. “Development of a monoclonal immunoassay selective for
chlorinated cyclodiene insecticides”.
J. Agric. Food Chem. 52, 2776 (2004).
252. S. Encinas, N. Belmadoui, M. J. Climent, S. Gil,
M. A. Miranda “Photosensitization of
thymine nucleobase by benzophenone derivatives as models for photoinduced DNA
damage: Paterno-Buechi vs energy and electron transfer processes”. Chem. Res. Toxicol. 17,
857 (2004).
253. M. De Sousa, M. Kluciar, S. Abad, M. A. Miranda, B.
De Castro, U. Pischel. “An inhibit (INH) molecular logic gate based on
1,8-naphthalimide-sensitised europium luminescence”. Photochem.
Photobiol. Sci. 3, 639 (2004).
254. A. M. Amat, A. Arques, F.
Lopez, S. Segui, M. A. Miranda. “Abatement of industrial sulfonic pollutants by
ozone and UV radiation”.
Environ. Eng. Sci. 21, 485 (2004).
255. V. Lhiaubet-Vallet, Z. Sarabia, F. Bosca, M. A.
Miranda. “Human serum albumin-mediated
stereodifferentiation in the triplet state behavior of (S)- and
(R)-carprofen. J. Am. Chem. Soc. 126, 9538 (2004).
256. V. Lhiaubet-Vallet, J. Trzcionka, S. Encinas, M.
A. Miranda, N. Chouini-Lalanne. “The triplet state of a N-phenylphthalimidine
with high intersystem crossing efficiency: Characterization by transient
absorption spectroscopy and DNA sensitization properties”. J. Phys. Chem.
B 108, 14148 (2004).
257. M. C. Cuquerella, F. Bosca, M. A. Miranda. “Photonucleophilic aromatic substitution of 6-fluoroquinolones in basic
media: triplet quenching by hydroxide anion”. J. Org. Chem. 69,
7256 (2004).
258. L. Llauger, M. A. Miranda, G. Cosa, J. C.
Scaiano. “Comparative study of the reactivities of substituted
3-(benzoyl)benzyl carbanions in water and in DMSO”. J. Org. Chem. 69, 7066 (2004).
259.
J. Perez-Prieto, S.E. Stiriba, M. Gonzalez-Bejar, L. R. Domingo, M. A.
Miranda. “Diels-Alder reaction between indoles and
cyclohexadienes photocatalyzed by p,p* aromatic ketones”. Org. Lett. 6,
3905 (2004).
260. A. M. Amat, A. Arques, M. A. Miranda, S. Segui. “Photo-Fenton reaction
for the abatement of commercial surfactants in a solar pilot plant”. Solar Energy 77,
559 (2004).
261. A. M. Amat, A. Arques, S. H. Bossmann, A. M. Braun, S. Goeb, M. A.
Miranda, E. Oliveros. “Oxidative
degradation of 2,4-xylidine by photosensitization with 2,4,6-triphenylpyrylium:
homogeneous and heterogeneous catalysis”. Chemosphere 57, 1123 (2004).
262. A. Caballero, R. Tormos,
A. Espinosa, M. D. Velasco, A. Tarraga, M. A. Miranda, P. Molina. “Selective fluorescence sensing of Li+ in an aqueous environment by a
ferrocene-anthracene-linked dyad”. Org. Lett. 6 4599 (2004).
263. B. Branchi,
M. Bietti, G. Ercolani, M. A. Izquierdo, M. A. Miranda, L. Stella. “The role of aromatic radical cations and benzylic
cations in the 2,4,6-triphenylpyrylium tetrafluoroborate photosensitized
oxidation of ring-methoxylated benzyl alcohols in CH2Cl2 solution”. J. Org. Chem. 69, 8874 (2004).
264. J. Perez-Prieto, S.-E. Stiriba, F. Bosca, A. Lahoz, L.
R. Domingo, F. Mourabit, S. Monti, M. A. Miranda. “Geometrical effects on the intramolecular quenching
of p,p aromatic ketones by phenols and indoles”. J. Org.
Chem. 69, 8618 (2004).
265. M. C. Jimenez, M. A.
Miranda, R. Tormos, I. Vaya. “Characterisation
of the lowest singlet and triplet excited states of S-flurbiprofen”. Photochem. Photobiol. Sci. 3, 1038 (2004).
266. L. B. Jimenez, S. Encinas,
M. A. Miranda, M. L. Navacchia, C. Chatgilialoglu. “The photochemistry of 8-bromo-2'-deoxyadenosine. A
direct entry to cyclopurine lesions”. Photochem. Photobiol. Sci. 3,
1042 (2004).
267. S. Encinas, M. J. Climent, S. Gil, U. O.
Abrahamsson, J. Davidsson, M. A. Miranda. “Singlet excited-state interactions
in naphthalene-thymine dyads”. ChemPhysChem 5, 1704 (2004).
LECTURES:
- Jan 1987. Institute of
Pharmaceutical Chemistry, Universität Mainz (Germany). Invited lecture.
- Apr 1990. Research Center,
Laboratorios Menarini, Badalona (Spain). Invited lecture.
- Sept 1991. VII Congreso de la Sociedad Española
de Química Terapéutica, Jaca (Spain). Plenary
lecture.
- May 1992. VII
Journées Franco-espagnoles de Chimie Organique, Pyla sur Mer (France). Plenary lecture.
- Sept 1992. XXIV Reunión Bienal
de la Real Sociedad
Española de Química, Torremolinos (Spain). Invited lecture.
- Nov 1992. II Simposio de la SECAL, Barcelona (Spain). Invited lecture.
- May 1993. Universidad de Castilla-La
Mancha, Ciudad Real (Spain). Invited lecture.
- Sept 1993. V Congress of the
European Society for Photobiology, Marburg (Germany). Invited lecture.
- Sept 1993. Institute of Organic
Chemistry, Universität Würzburg (Germany). Invited lecture.
- Jun 1994. II Jornadas de
Validación de Modelos Alternativos in vitro en la Industria
Farmacéutica y Cosmética,
Peñíscola (Spain). Invited lecture.
-
Sept 1994. Universidad de Barcelona (Spain), Facultad de Farmacia. Short course
(7 lectures).
-
Abr 1995. Fundación Bosch Gimpera/Universidad de Barcelona (Spain). Invited lecture.
- Sept 1995. Universidad de La Rioja (Spain). Invited
lecture.
- Sept 1995. Universidad de Barcelona (Spain). Short
course (7 lectures).
- Sept 1996. EUROTOX, Alicante (Spain). Invited lecture.
-
Dec 1996. Universitat de Valencia (Estudi General), Departamento de
Química Física. Invited lecture.
- March 1997. XVI Reunión Bienal
del Grupo de Orgánica de la Real Sociedad Española de Química. Ciudad Real (Spain). Invited lecture.
- Sept 1997. VII Congress of the
European Society for Photobiology. Stresa (Italy). Special
lecture.
- Sept 1997. VII Congress of the
European Society for Photobiology. Stresa (Italy). Invited lecture.
- Feb 1998. 2nd Euro-Mediterranean
Conference on Applications of
Photobiology and Laser Technologies in Medicine and Environment. Cairo (Egypt).
Plenary Lecture.
- May 1998. Bayer AG. Monheim
(Germany). Invited lecture.
- January 1999. Universidad
Simón Bolívar. Caracas (Venezuela). Three
invited lectures.
- January 1999. Universidad
Central de Venezuela. Caracas (Venezuela). Invited
lecture.
- January 1999. Instituto Venezolano
de Investigaciones Científicas. Caracas
(Venezuela). Invited lecture.
- January 1999. Universidad de Los
Andes. Mérida (Venezuela). Invited lecture.
- April 1999. 3rd Euro-Mediterranean
Conference on Photobiology. Meknes (Morocco). Plenary lecture.
- September 1999. 8th Congress of
the European Society for Photobiology. Granada (Spain). Invited lecture.
- September 1999. 6 Encontro
Latino-Americano de Fotoquimica e Fotobiologia. Teressopolis
(Brazil). Plenary lecture.
- October 1999. International
Meeting on Excited States in Molecules and Solids. Tarragona (Spain). Invited
lecture.
- November 1999. Universität
Karlsruhe (Germany). Two invited lectures.
- November 1999. University of Catania (Italy). Invited lecture.
- July 2000, 13th International Conference on Photobiology. San Francisco (USA).
Invited lecture.
- July 2000, XVIII IUPAC Symposium on Photochemistry. Dresden (Germany).
Plenary lecture.
-
September 2000. 3rd Spanish-Italian Symposium on Organic Chemistry.
Benalmadena (Spain). Invited lecture.
-
May 2001. University of Ottawa (Canada). Invited lecture.
-
September 2001. 9th
Congress of the European Society for Photobiology. Lillehammer (Norway). 2
Invited Lectures.
-
October 2001. University of
Athens (Greece). Invited lecture.
-
October 2001. University of
Heraklion (Greece). Invited lecture.
-
June 2002. XVIIIth
International Radical Ion Conference. Heigenbrücken (Germany). Plenary
lecture.
-
September 2002. I
Congreso de Química Orgánica del Mediterráneo. Alicante (Spain). Plenary lecture.
-
November 2002. Consiglio
Nazionalle delle Ricerche (CNR-ISOF). Bologna (Italy).
Invited lecture.
-
June 2003. 2nd Mediterranean Meeting on Photochemistry, Giardini Naxos
(Italy). Plenary Lecture.
-
July 2003. Centennial of the Spanish Royal Societies of Physics and Chemistry,
Madrid. Invited Lecture.
-
July 2003. XXI International
Conference on Photochemistry, Nara (Japan). Invited lecture.
-
September 2003. X Congress
of the European Society for Photobiology, Vienna (Austria). Invited lecture.
-
November 2003. XIV National
Symposium on Organic Chemistry, Rosario (Argentina). Plenary lecture.
-
November 2003. University
of Buenos Aires (Argentina). Invited lecture
-
November 2004. VIII Encuentro
Latino-Americano de Fotoquímica y Fotobiología. La Plata (Argentina). Plenary lecture.
-
November 2004. Universidad
Nacional de Cordoba (Argentina). Invited lecture.
DOCTORAL THESES:
1.
Hermenegildo García. Universidad de Valencia, 1983.
2.
María-Rosa Díaz-Mondéjar. Universidad
de
Valencia,1983.
3. Luis Fillol. Universidad de Valencia,
1986.
4. Sara Iborra. Universidad de Valencia, 1987.
5. Isabel Morera. Universidad de Valencia,
1988.
6. Celia Belled. Universidad de Valencia,
1988.
7. Ana M. Amat. Universidad de Valencia,
1988.
8. María-José Sabater.
Universidad de Valencia, 1991.
9. Francisco Boscá. Universidad de
Valencia, 1992.
10. Nieves Canudas. Universidad
Politécnica de Valencia. 1994.
11. Luis A. Martínez. Universidad
Politécnica de Valencia. 1995.
12. M. Consuelo Jiménez. Universidad
Politécnica de Valencia. 1997.
13. Zaideth Sarabia. Universidad
Politécnica de Valencia. 1998.
14. Susana Encinas. Universidad
Politécnica de Valencia. 1998.
15. Angel Cantín. Universidad
Politécnica de Valencia. 1998.
16. Enrique Font. Universidad de Valencia.
1999.
17. Francisco Galindo. Universidad
Politécnica de Valencia. 1999.
18. Amparo Espinós. Uiversidad
Politécnica de Valencia. 1999.
19. M. Dolores Planes. Universidad Politécnica de
Valencia. 2000.
20. Antonio Arques. Universidad
Politécnica de Valencia. 2001.
21. Agustín Lahoz. Universidad de
Valencia. 2001.
22. Abdelouahid Samadi. Universidad
Politécnica de Valencia. 2001.
23. M. Angeles Izquierdo. Universidad Politécnica de Valencia. 2003.
24. M. Consuelo Cuquerella. Universidad Politécnica de Valencia.
2004.
M. Sc. THESES:
1. Hermenegildo García. Universidad de
Valencia, 1980.
2. Adela Solano. Universidad de
Valencia,1980.
3. María-Rosa
Díaz-Mondéjar. Universidad de Valencia, 1981.
4. Federica Roquet-Jalmar. Universidad de Valencia, 1981.
5. Isabel Morera. Universidad de Valencia,
1983.
6. Mercedes Quiles. Universidad de Valencia,
1983.
7. Sara Iborra. Universidad de Valencia,
1984.
8. Roberto Lozano. Universidad de Valencia,
1985.
9. Celia Belled. Universidad de Valencia,
1985.
10. Ana M. Amat. Universidad de Valencia,
1986.
11. María-José Castelló.
Universidad de Valencia,1986.
12. M. Carmen Barberá. Universidad de Valencia,
1986.
13. Alicia Casado. Universidad Complutense de Madrid, 1987.
14. Francisco Boscá. Universidad de
Valencia, 1988.
15. Felipe Algarra. Universidad de Valencia,
1988.
16. Lirios Vañó. Universidad de
Valencia, 1989.
17. Miguel Pitarch. Universidad de Valencia,
1989.
18. M. Consuelo Jiménez. Universidad de Valencia,
1992.
19. Francisco Galindo. Universidad de
Valencia, 1995.
20. Enrique Font. Universidad de Valencia,
1996.
21. Agustín Lahoz. Universidad de
Valencia, 1998.
POST-DOCTORAL RESEARCH ASSOCIATES:
1. Hamid Sheikh
(Iran), Ph. D. University of Keele, UK (G. Jones). 1988-90.
2. Franklin Vargas (Venezuela). Ph. D. Universität Würzburg, D (W. Adam). 1989-90.
3. Fatemeh Mojarrad (Iran). Ph. D.
Universidad de Valencia (B. Abarca). 1991-94.
4. Nadia Suliman (Sudan). Ph. D. University of Manchester, UK (A. E. Tipping). 1993-94.
5. Francisco
Boscá (Spain). Ph. D. Universidad de Valencia (M. A. Miranda). Previous
post-docs University
of Illinois, USA (R. A. Larson) and North East Wales Institute, UK (P. Heelis).
1997-1999.
6. Bernd Kratzer
(Germany). Ph. D. Universität Heidelberg, D (H. A. Staab). 1998-99.
7. Maria Luisa Marín (Spain). Ph. D.
Universidad de Valencia (A. Abad). Previous post-
doc Imperial College
London, UK (D. Craig). 1998-2000.
8. Luis A. Martinez (Spain).
Ph. D.
Universidad de Valencia (M. A. Miranda). Previous
post-doc
Universität Karlsruhe, D (A. M. Braun and E. Oliveros). 1999-2001.
9. M. Consuelo Jiménez (Spain). Ph. D.
Universidad Politécnica de Valencia
(M. A.
Miranda). Previous post-doc University of Strasbourg , F (J. P.
Sauvage). 2000.
10. Zaideth Sarabia (Venezuela). Ph. D.
Universidad Politécnica de Valencia (M. A.
Miranda). Previous
post-doc University of Leiden, NL (G. M. J. Beijersbergen van
Henegouwen). 2000- 2002.
11. Susana Encinas (Spain). Ph.D. Universidad Politécnica de
Valencia (M. A.
Miranda). Previous post-doc CNR Bologna, I
(F. Barigelletti). 2001-2004.
12. Raquel E. Galian (Argentina). Ph. D.
Universidad Nacional de Córdoba, Argentina
(R. H. De Rossi).
2001-2003.
13. Virginie Lhiaubet
(France). Ph. D. Université Paul Sabatier, Toulouse, F (N. Paillous and
N. Chouini-Lalanne). 2001-
14. Inmaculada Andreu (Spain). Ph. D.
Universidad de Valencia (D. Cortés). 2002.
15. Uwe Pischel
(Germany). Ph. D. University of Basel, CH
(W. Nau). 2002-2003.
16.
Pavel Arsenyan (Latvia). Ph. D. University of Riga
(E. Lukevics ). 2003.
17.
Juan E. Argüello (Argentina). Ph. D. Universidad Nacional de
Córdoba, Argentina (A. Peñéñori). Previous post-doc University of Paris VI (J. M. Saveant/M. Robert).
2004-
GRANTS (as Principal
Investigator):
Comisión Asesora de
Investigación Científica y Técnica (CAICYT): Grant
1325/82.
Fondo de Investigaciones Sanitarias (FIS):
Grants 83/0982, 84/760 and 95/1498.
Dirección General de
Investigación Científica y Técnica (DGICYT): Grants PB
88-0494, SCI 182/89, PB 91-0540, PB 94-0539.
Dirección General de Enseñanza
Superior (DGES): Grants PB 97-0339 and HI 98-0230.
Dirección General de
Investigación: Grant CTQ2004-03811/BQU
Ministerio de Ciencia y Tecnología
(DGI): Grant BQU2001-2725.
European Union. Grants BMH 4-97-2590,
ERBFMBI-CT-97-2426,
HPMF-CT-1999-00338, HPMF-CT-2000-00611, HPMF-CT-2001-01228,
MCRTN-CT-2003-505086.
Generalitat Valenciana. Grants GV-CAPA00-20,
GR00-216, GR01-40, GRUPOS03/082.